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To clean a ring in a toilet bowl, sprinkle baking soda around the bowl of your toilet. I find it best to drain some of the water out of the toilet bowl, then sprinkle the powder around the ring, and scrub it with a cleaning rag. How to Use Vinegar and Baking Soda to Clean a Toilet Alternatively, you can submerge a pumice stone in your toilet bowl water for 15 minutes. How to clean stubborn toilet rings . This will work for most basic stains. Clean the toilet and flush it with water. This should work for rings that aren’t too large or stubborn. For very stubborn toilet stains (rust, etc.) use muriatic acid. In addition to this green clean solution, you can change baking soda with borax. Yes, you can clean toilet bowl rings with vinegar. As you try and get rid of the toilet ring, it is important to make sure that the method you pick does not leave you bowl badly scratched. Wait at least 1 hour, then moisten the baking soda with vinegar spray and use a toilet brush t